Separation and Preconcentration of Trace Inorganic Constituents by Ion Exchange

Commission on Microchemical Techniques and Trace Analysis Separation and Preconcentration of Trace Substances . I — Preconcentration for Inorganic Trace Analysis

Preconcentration in Inorganic Trace Analysis

Preconcentration in trace analysis lowers the detection limit, simplifies the treatment of a representatIve sample, facilitates calibration, reduces the need for various standard reference samples and frequently involves separation of the matrix in analysis of toxic, radioactive and expensive materials. In this paper, the types of preconcentration are considered and quantitative characteristics...

Application of Modified Nanoclay Sorbent for Separation and Preconcentration Trace Amount of Cobalt

The present article reports on the application of modified organo nanoclay as a green, easily prepared and stable solid sorbent for the preconcentration of trace cobalt ion in aqueous solution. The organo nanoclay was modified by adsorption of 5-(4-dimethyl amino-benzylidene) rhodanin reagent onto it. The sorption of Co2+ ions was quantitative in the pH range of 7.0 to 8.5, whereas quantitative...

Nitrogen Isotope Separation by Ion Exchange Chromatography

Enriched stable isotopes of many elements have been widely used in many aspects and such isotopes have been primarily used as the tracer for agricultural and biochemical studies and the availability of the isotopically labeled compounds have been now extensively increasing. Chemical exchange separation of isotopes is based on the equilibrium fractionation of isotopes between two phases, ion exc...

Semipermeable ion-exchange membranes as a preconcentration matrix for trace analysis by electrochemical and neutron-activation techniques.

Ion-exchange membranes were used in conjunction with neutron-activation analysis and anodic stripping voltammetry for the determination of certain trace metal ions. The various parameters which govern the applicability, limitations and sensitivity of the methods were investigated. A new membrane "barrier" electrode assembly was introduced and found to be useful for the anodic stripping determin...